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NOx formation from the combustion of monodisperse n-heptane sprays doped with fuel-nitrogen additives
Journal article   Peer reviewed

NOx formation from the combustion of monodisperse n-heptane sprays doped with fuel-nitrogen additives

Hamid Sarv and Nicholas P. Cernansky
Combustion and flame, v 76(3&4), pp 265-283
01 Jun 1989

Abstract

PROPELLANTS AND FUELS
A series of experiments with simulated synthetic fuels were conducted in order to investigate the effect of droplet size on the conversion of fuel-nitrogen to NOx. Pyridine and pyrrole were added to n-heptane as nitrogen-containing additives and burned as monodisperse fuel droplets under various operating conditions in a spray combustion facility. The experimental results indicate that under stoichiometric and fuel-rich conditions, reducing the droplet size increases the efficiency of fuel-N conversion to NOx. This observation is associated with improved oxidation of the pyrolysis fragments of the additive by better oxygen penetration through the droplet flame zone. The dominant reactions by which fuel-N is transformed to NOx were also considered analytically by a premixed laminar flame code. The calculations are compared to the small droplet size results.

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Web of Science research areas
Energy & Fuels
Engineering, Chemical
Engineering, Mechanical
Engineering, Multidisciplinary
Thermodynamics
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