Journal article
Ni(II), Co(II) and Mn(II) tris(pyrazolyl)borate complexes with 2,6-di- tert-butyl-4-carboxy-phenol: Formation of coordinated phenoxyl radical
Inorganic chemistry communications, v 8(10), pp 932-935
2005
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Abstract
It was found that coordination of Ni and Co complexes to 2,6-di-
tert-butyl-4-carboxy-phenoxyl led to stabilization of this radical.
Ni(II), Co(II) and Mn(II) tris(pyrazolyl)borate complexes with 2,6-di-
tert-butyl-4-carboxy-phenol were synthesized and characterized crystallographically (Ni and Co complexes), spectroscopically and electrochemically. It was found that oxidation of Ni and Co complexes resulted in the formation of coordinated phenoxyl radical and diphenoquinone, whereas only quinone formed in the case of Mn complex and free 2,6-di-
tert-butyl-4-carboxy-phenol.
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Details
- Title
- Ni(II), Co(II) and Mn(II) tris(pyrazolyl)borate complexes with 2,6-di- tert-butyl-4-carboxy-phenol: Formation of coordinated phenoxyl radical
- Creators
- Anastasiya V. Yakovenko - L.V. Pisarzhevskii Institute of Physical ChemistrySergey V. Kolotilov - L.V. Pisarzhevskii Institute of Physical ChemistryAnthony W. Addison - Drexel UniversitySwiatoslaw Trofimenko - University of DelawareGlenn P.A. Yap - University of DelawareVictoria Lopushanskaya - L.V. Pisarzhevskii Institute of Physical ChemistryVitaly V. Pavlishchuk - L.V. Pisarzhevskii Institute of Physical Chemistry
- Publication Details
- Inorganic chemistry communications, v 8(10), pp 932-935
- Publisher
- Elsevier
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Chemistry
- Web of Science ID
- WOS:000232191400017
- Scopus ID
- 2-s2.0-24944570005
- Other Identifier
- 991019168758304721
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- Collaboration types
- Domestic collaboration
- International collaboration
- Web of Science research areas
- Chemistry, Inorganic & Nuclear