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Nitrogen-doped carbon microfibers with porous textures
Journal article   Peer reviewed

Nitrogen-doped carbon microfibers with porous textures

Yanru Fan, Zongbin Zhao, Quan Zhou, Guodong Li, Xuzhen Wang, Jieshan Qiu and Yury Gogotsi
Carbon (New York), v 58, pp 128-133
01 Jul 2013

Abstract

Chemistry Chemistry, Physical Materials Science Materials Science, Multidisciplinary Physical Sciences Science & Technology Technology
Nitrogen-doped carbon microfibers (N-CMFs) with porous textures have been synthesized by means of a floating catalyst chemical vapor deposition (FCCVD) with anhydrous ferric chloride as a catalyst precursor and melamine as both the carbon and nitrogen source. X-ray photoelectron spectroscope (XPS) characterization of the as-prepared N-CNFs reveals nitrogen atoms in the N-CMFs are mainly in the form of pyridine-like nitrogen and graphitic nitrogen. The sublimation and subsequent gas phase reduction of FeCl3 in H-2 produces Fe micro-particles with high catalytic activity that leads to the growth of the microfibers. The electrochemical studies have shown that N-CMFs have a larger capacitance than the pure CMFs, showing promise for use as electrode materials in supercapacitors. (C) 2013 Elsevier Ltd. All rights reserved.

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Chemistry, Physical
Materials Science, Multidisciplinary
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