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On Equilibrium Ga Intergranular Films in Cr2GaC
Journal article   Open access

On Equilibrium Ga Intergranular Films in Cr2GaC

ZhengMing Sun, Michel W. Barsoum, Yamei Zhang and Hitoshi Hashimoto
Materials research letters, v 1(2)
01 Jun 2013
url
https://doi.org/10.1080/21663831.2013.794374View
Published, Version of Record (VoR)CC BY-NC V4.0 Open

Abstract

DSC Intergranular Films Wetting Whiskers
The presence of equilibrium intergranular films (IGFs) in metallic systems has long been postulated; compelling evidence for this idea, however, is still lacking. Herein differential scanning calorimetry, in the−60°C to 70°C temperature range, on bulk and Cr 2 GaC powders was carried out. A sharp endothermic trough, roughly 50°C below the melting point of bulk pure Ga, in the powdered samples was taken to be strong evidence for the presence of IGFs in the latter. The troughs for the sintered body were much more diffuse suggesting that in this case, a distribution of grain boundary thicknesses exists. A temperature dependent adsorption energy is postulated to explain the reversible extrusion and resorption of 100 μm thick Ga micro-pillars.

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Collaboration types
Domestic collaboration
International collaboration
Web of Science research areas
Materials Science, Multidisciplinary
Metallurgy & Metallurgical Engineering
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