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Optical properties of Ti3SiC2 and Ti4AlN3
Journal article   Open access   Peer reviewed

Optical properties of Ti3SiC2 and Ti4AlN3

S. Li, Rajeev Ahuja, M. W. Barsoum, P. Jena and Börje Johansson
Applied physics letters, v 92(22), p221907
2008
url
https://doi.org/10.1063/1.2938862View
Published, Version of Record (VoR)Open Access (License Unspecified) Open

Abstract

band electronic-structure tin
The dielectric functions of the MAX phases, Ti3SiC2 and Ti4AlN3, have been determined from first principles calculations. We compared the dielectric functions and the reflectivity spectra of Ti3SiC2 and Ti4AlN3 with those of TiC and TiN. The optical spectra were analyzed by means of the electronic structure, which provides theoretical understanding of the conduction mechanism of these two phases. We found that Ti4AlN3 can be used to avoid solar heating and also increase the radiative cooling due to the increased thermal emittance as compared to TiN. Ti4AlN3 can therefore be a candidate coating material for temperature control of space vehicles.

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Physics, Applied
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