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Optoelectronic property and sensing applications of crystalline nano/microwires of decacyclene
Journal article   Peer reviewed

Optoelectronic property and sensing applications of crystalline nano/microwires of decacyclene

Hong Wang, Xiaohe Xu, Ligui Li, Catherine Yang and Hai-Feng Ji
Micro & nano letters, v 6(9), pp 763-766
01 Sep 2011

Abstract

Materials Science Materials Science, Multidisciplinary Nanoscience & Nanotechnology Science & Technology Science & Technology - Other Topics Technology
The characterisation and potential sensing applications of nano- and microwires of decacyclene are reported in this study. Attenuated total reflection infrared and differential thermal analyses reveal that the nano/microstructures are composed of aggregated decacyclene molecules that are held by pi-pi interactions. Transmission electron microscopy images and the electron diffraction patterns show that, in the nanowires, the decacyclene molecules are oriented with their long axis perpendicular to the wires and the pi-pi stacking direction parallel to the wire. Cross-optical polarised microscopy results shows a birefringent crystal structure of the decacyclene crystalline wires. Fluorescent imaging shows that the crystalline wires might be used as a waveguide material. Both the conductivity and fluorescence of the nanobelts change selectively in the presence of vapour of nitrobenzene, a representative nitroaromatic, suggesting that the nanowires of decacyclene may be used for selective detection of explosives.

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Collaboration types
Domestic collaboration
Web of Science research areas
Materials Science, Multidisciplinary
Nanoscience & Nanotechnology
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