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Overview of the synthesis of MXenes and other ultrathin 2D transition metal carbides and nitrides
Journal article   Open access   Peer reviewed

Overview of the synthesis of MXenes and other ultrathin 2D transition metal carbides and nitrides

Louisiane Verger, Chuan Xu, Varun Natu, Hui-Ming Cheng, Wencai Ren and Michel W. Barsoum
Current opinion in solid state & materials science, v 23(3), pp 149-163
01 Jun 2019
url
https://doi.org/10.1016/j.cossms.2019.02.001View
Published, Version of Record (VoR)Open Access (License Unspecified) Open

Abstract

Materials Science Materials Science, Multidisciplinary Physical Sciences Physics Physics, Applied Physics, Condensed Matter Science & Technology Technology ESI Highly Cited Paper (Incites)
In 2011, a new family of two dimensional (2D) carbides, carbonitrides and nitrides - labeled MXenes - was discovered. Since then the number of papers on these materials has increased exponentially for several reasons amongst them: their hydrophilic nature, excellent electronic conductivities and ease of synthesizing large quantities in water. This unique combination of properties and ease of processing has positioned them as enabling materials for a large, and quite varied, host of applications from energy storage to electromagnetic shielding, transparent conductive electrodes, electrocatalysis, to name a few. Since the initial synthesis of Ti3C2 in hydrofluoric acid, many more compositions were discovered, and different synthesis pathways were explored. Most of the work done so far has been conducted on top-down synthesis where a layered parent compound is etched and then exfoliated. Three bottom-up synthesis methods, chemical vapor deposition, a template method and plasma enhanced pulsed laser deposition have been reported. The latter methods enable the synthesis of not only high-quality ultrathin 2D transition metal carbide and nitride films, but also those that could not be synthesized by selective etching. This article reviews and summarizes the most important breakthroughs in the synthesis of MXenes and high-quality ultrathin 2D transition metal carbide and nitride films.

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Collaboration types
Domestic collaboration
International collaboration
Web of Science research areas
Materials Science, Multidisciplinary
Physics, Applied
Physics, Condensed Matter
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