In 2011, a new family of two dimensional (2D) carbides, carbonitrides and nitrides - labeled MXenes - was discovered. Since then the number of papers on these materials has increased exponentially for several reasons amongst them: their hydrophilic nature, excellent electronic conductivities and ease of synthesizing large quantities in water. This unique combination of properties and ease of processing has positioned them as enabling materials for a large, and quite varied, host of applications from energy storage to electromagnetic shielding, transparent conductive electrodes, electrocatalysis, to name a few. Since the initial synthesis of Ti3C2 in hydrofluoric acid, many more compositions were discovered, and different synthesis pathways were explored. Most of the work done so far has been conducted on top-down synthesis where a layered parent compound is etched and then exfoliated. Three bottom-up synthesis methods, chemical vapor deposition, a template method and plasma enhanced pulsed laser deposition have been reported. The latter methods enable the synthesis of not only high-quality ultrathin 2D transition metal carbide and nitride films, but also those that could not be synthesized by selective etching. This article reviews and summarizes the most important breakthroughs in the synthesis of MXenes and high-quality ultrathin 2D transition metal carbide and nitride films.
Overview of the synthesis of MXenes and other ultrathin 2D transition metal carbides and nitrides
Creators
Louisiane Verger - Drexel University
Chuan Xu - Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences Shenyang 110016 PR China
Varun Natu - Drexel University
Hui-Ming Cheng - University of Science and Technology of China
Wencai Ren - University of Science and Technology of China
Michel W. Barsoum - Drexel University
Publication Details
Current opinion in solid state & materials science, v 23(3), pp 149-163
Publisher
Elsevier
Number of pages
15
Grant note
51325205; 51290273; 51521091 / National Science Foundation of China; National Natural Science Foundation of China (NSFC)
KGZD-EW-T06 / Chinese Academy of Sciences
621-2014-4890 / Swedish Research Council; European Commission
SYNL-T.S. K Research Fellowship
XDB30000000 / Strategic Priority Research Program of Chinese Academy of Sciences; Chinese Academy of Sciences
Youth Innovation Promotion Association of Chinese Academy of Sciences
Resource Type
Journal article
Language
English
Academic Unit
Materials Science and Engineering
Web of Science ID
WOS:000483415300004
Scopus ID
2-s2.0-85062420588
Other Identifier
991019168425904721
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