Journal article
Oxidation of 1,3-dicarbonyl compounds using (camphorylsulfonyl)oxaziridines
Tetrahedron, v 54(35), pp 10481-10492
1998
Featured in Collection : UN Sustainable Development Goals @ Drexel
Abstract
The oxidation of 1,3-dicarbonyl compounds with (camphorylsulfonyl)oxaziridines
2 was studied in both cyclic and acyclic systems. Two reaction pathways were identified: enolate α-hydroxylation and a novel Baeyer-Villiger type oxidation. The Baeyer-Villiger oxidation product was observed only for the ketones and arises via rearrangement of an alkoxy epoxide. Synthetically useful ee's (82–95%) were observed only for enolates of β-ketoesters where the keto group is part of a 6-membered ring.
The oxidation of 1,3-dicarbonyl compounds with (camphorylsulfonyl)oxaziridines
2 was studied in both cyclic and acyclic systems. Two reaction pathways were identified: enolate α-hydroxylation and a novel Baeyer-Villiger type oxidation.
Metrics
Details
- Title
- Oxidation of 1,3-dicarbonyl compounds using (camphorylsulfonyl)oxaziridines
- Creators
- Franklin A. Davis - Temple UniversityHu Liu - Temple UniversityBang-Chi Chen - Drexel UniversityPing Zhou - Drexel University
- Publication Details
- Tetrahedron, v 54(35), pp 10481-10492
- Publisher
- Elsevier
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- [Retired Faculty]
- Web of Science ID
- WOS:000075312400021
- Scopus ID
- 2-s2.0-0032572867
- Other Identifier
- 991019168529404721
UN Sustainable Development Goals (SDGs)
This publication has contributed to the advancement of the following goals:
InCites Highlights
Data related to this publication, from InCites Benchmarking & Analytics tool:
- Collaboration types
- Domestic collaboration
- Web of Science research areas
- Chemistry, Organic