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Performance and pathways of electrochemical cyclohexane oxidation
Journal article   Open access   Peer reviewed

Performance and pathways of electrochemical cyclohexane oxidation

Nuwan Harsha Attanayake and Maureen Tang
Current opinion in electrochemistry, v 30, p100791
01 Dec 2021
url
https://doi.org/10.1016/j.coelec.2021.100791View
Accepted (AM)Open Access (Publisher-Specific) Open

Abstract

Chemistry Chemistry, Physical Electrochemistry Materials Science Materials Science, Multidisciplinary Physical Sciences Science & Technology Technology
Falling costs of electricity from renewable and non-renewable sources have motivated interest in electrochemical production of chemicals and fuels. Among commodity chemicals, the production of KA oil (cyclohexanol and cyclohexanone) from cyclohexane is attractive as selective alkane oxidation remains a major industrial challenge. Although this reaction has been demonstrated in the literature, its fundamental chemistry remains poorly understood. This review identifies possible pathways for the reaction mechanism, their experimental support, and remaining critical gaps in molecular understanding of electrochemical cyclohexane oxidation to KA oil.

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Web of Science research areas
Chemistry, Physical
Electrochemistry
Materials Science, Multidisciplinary
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