Journal article
Poly[tetraaqua-di-mu(4)-malonato-barium(II)cadmium(II)]
Acta crystallographica. Section E, Structure reports online, v 67, pp M23-U362
01 Jan 2011
PMID: 21522548
Featured in Collection : UN Sustainable Development Goals @ Drexel
Abstract
In the title complex, [BaCd(C3H2O4)2(H2O)4](n), the Ba-II atoms, located on crystallographic twofold axes, adopt slightly distorted square-antiprismatic coordination geometries, while the Cd-II atoms, which lie on crystallographic centres of symmetry, have a distorted octahedral coordination. Each malonate dianion binds two different Cd-II atoms and two different Ba-II atoms. This connectivity generates alternating layers along [100] in the structure, with one type containing Cd-II cations and malonate dianions, while the other is primarily composed of Ba-II ions and coordinated water molecules. The water molecules also participate in extensive O-H center dot center dot center dot O hydrogen bonding.
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Details
- Title
- Poly[tetraaqua-di-mu(4)-malonato-barium(II)cadmium(II)]
- Creators
- Ming-Lin Guo - Tiangong UniversityWen-Jun Gao - Tiangong UniversityCong-Cong LuoLong Liu - Tiangong University
- Publication Details
- Acta crystallographica. Section E, Structure reports online, v 67, pp M23-U362
- Publisher
- Wiley
- Number of pages
- 12
- Grant note
- Tianjin Polytechnic University
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Neurobiology and Anatomy; College of Medicine; Drexel University
- Web of Science ID
- WOS:000285628900026
- Scopus ID
- 2-s2.0-78650733715
- Other Identifier
- 991020099920804721
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- Web of Science research areas
- Crystallography