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Probing diffusion of single nanoparticles at water-oil interfaces
Journal article   Peer reviewed

Probing diffusion of single nanoparticles at water-oil interfaces

Dapeng Wang, Stoyan Yordanov, Harsha Mohan Paroor, Ashis Mukhopadhyay, Christopher Y Li, Hans-Jürgen Butt and Kaloian Koynov
Small (Weinheim an der Bergstrasse, Germany), v 7(24), pp 3502-3507
16 Dec 2011
PMID: 22072585

Abstract

Viscosity Nanoparticles - chemistry Quantum Dots Water - chemistry Spectrometry, Fluorescence Kinetics Oils - chemistry Diffusion Alkanes - chemistry
The diffusion of nanoparticles at a water-alkane interface is studied using fluorescence correlation spectroscopy. Hydrophilic and hydrophobic quantum dots of 5, 8, and 11 nm radius are used. A slow-down of nanoparticle diffusion at the liquid-liquid interface is observed. The effect is most evident when the viscosities of both liquid phases are similar, here, at the water-decane interface. In this case, the interfacial diffusion coefficients of the hydrophilic particles are 1.5 times and those of the hydrophobic particles 2 times lower than the corresponding bulk values.

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Collaboration types
Domestic collaboration
International collaboration
Web of Science research areas
Chemistry, Multidisciplinary
Chemistry, Physical
Materials Science, Multidisciplinary
Nanoscience & Nanotechnology
Physics, Applied
Physics, Condensed Matter
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