Journal article
Pseudocapacitance and excellent cyclability of 2,5-dimethoxy-1,4-benzoquinone on graphene
Energy & environmental science, v 9(8), pp 2586-2594
2016
Abstract
Electrochemically active organic materials are emerging as low cost, naturally abundant and sustainable alternatives to their metal-based counterparts. However, their usage in energy storage systems is mainly hindered by their poor conductivity, which results in capacitance fade upon cycling. Here, we report a redox-active xerogel composed of 2,5-dimethoxy-1,4-benzoquinone (DMQ) decorated on reduced graphene oxide (rGO) sheets via a hydrothermal method as a high capacitance and long cycle life pseudocapacitive electrode. DMQ not only provided stable redox-active centers but also served as a spacer to avoid rGO sheets aggregation and led to a three-dimensional (3D) hierarchical electrode architecture. When a binder-free 50 μm thick rolled film was tested as a pseudocapacitive electrode, it exhibited an excellent capacitance of 650 F g−1 at 5 mV s−1 (780 F cm−3) in 1 M sulfuric acid, outperforming a large number of reported organic and inorganic electrodes. Most importantly, optimized electrodes showed an excellent capacitance retention of 99% after 25 000 cycles at 50 mV s−1. Density functional theory (DFT) calculations are further used to understand the charge storage mechanism, the preferred orientation of the adsorbed molecules, charge density distribution and density of states. Our combined experimental and theoretical findings demonstrate that the careful selection of the conductive substrate, electrode architecture and organic molecules plays a crucial role in achieving high capacitance and long cycling performance.
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150 citations in Scopus
Details
- Title
- Pseudocapacitance and excellent cyclability of 2,5-dimethoxy-1,4-benzoquinone on graphene
- Creators
- Muhammad Boota - A. J. Drexel Nanomaterials Institute and Department of Materials Science and Engineering, Drexel University, Philadelphia, USAChi Chen - A. J. Drexel Nanomaterials Institute and Department of Materials Science and Engineering, Drexel University, Philadelphia, USA, School of Optical and Electronic InformationMatthieu Bécuwe - Laboratoire de Réactivité et Chimie des Solides (LRCS), UMR CNRS 7314, Université de Picardie Jules Verne (UPJV), 80039 Amiens, FranceLing Miao - School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan, People's Republic of ChinaYury Gogotsi - A. J. Drexel Nanomaterials Institute and Department of Materials Science and Engineering, Drexel University, Philadelphia, USA
- Publication Details
- Energy & environmental science, v 9(8), pp 2586-2594
- Publisher
- Royal Society of Chemistry
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Materials Science and Engineering
- Scopus ID
- 2-s2.0-84982947829
- Other Identifier
- 991014970039504721