Journal article
Reaction Kinetics and Thermodynamic Aspects of Thermoreversibly Cross-Linked Polymer Networks
Macromolecular chemistry and physics, v 214(16), pp 1798-1805
26 Aug 2013
Abstract
The Diels-Alder reaction of furan and maleimide is used to prepare reversibly cross-linking polymer gels consisting of furan-bearing polymer chains and bismaleimides. The roles of chain length, stoichiometry, and concentration on gelation kinetics and other properties are evaluated. Additionally, kinetics of the Diels-Alder reactions in the gelling system are compared with the kinetics of small molecule systems. By combining spectroscopic and rheological techniques, a mechanochemical analysis is performed.
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Details
- Title
- Reaction Kinetics and Thermodynamic Aspects of Thermoreversibly Cross-Linked Polymer Networks
- Creators
- Amy M. Peterson - Drexel UniversityGiuseppe R. Palmese - Drexel University
- Publication Details
- Macromolecular chemistry and physics, v 214(16), pp 1798-1805
- Publisher
- Wiley
- Number of pages
- 8
- Grant note
- W911NF-06-2-0013 / US Army Research Laboratory under the Army Materials Center of Excellence Program National Science Foundation Graduate Research Fellowship; National Science Foundation (NSF)
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Chemical and Biological Engineering
- Web of Science ID
- WOS:000327738100004
- Scopus ID
- 2-s2.0-84882286205
- Other Identifier
- 991019168033404721
InCites Highlights
Data related to this publication, from InCites Benchmarking & Analytics tool:
- Collaboration types
- Domestic collaboration
- Web of Science research areas
- Polymer Science