Journal article
Ruthenium(II) complexes of the tetradentate polypyridyl thioether 1,2-bis[3′-(2″-pyridyl)-1′-thiapropyl]benzene
Polyhedron, v 179, 114367
15 Mar 2020
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Abstract
Several new Ru(II) polypyridyl complexes of the novel tetradentate thioether 1,2-bis[3′-(2″-pyridyl)-1′-thiapropyl]benzene (Ppes) form from the dinuclear ruthenium(II) complex [{Ru(Ppes)}2(µ-Cl)2]2+via reaction with various bidentate diimines. Facile symmetrical bridge cleavage occurs, producing mononuclear complexes of the form [Ru(Ppes)(L)]2+, where L is the bidentate diimine.
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Several new Ru(II) polypyridyl complexes of the novel tetradentate thioether 1,2-bis[3′-(2″-pyridyl)-1′-thiapropyl]benzene (Ppes) form from the dinuclear ruthenium(II) complex [{Ru(Ppes)}2(µ-Cl)2]2+via reaction with various bidentate diimines. Facile symmetrical bridge cleavage occurs, producing mononuclear complexes of the form [Ru(Ppes)(L)]2+, where L is the bidentate diimine. Redox chemistry shows single-electron Ru(II) → Ru(III) oxidations over a wide range of potentials.
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Details
- Title
- Ruthenium(II) complexes of the tetradentate polypyridyl thioether 1,2-bis[3′-(2″-pyridyl)-1′-thiapropyl]benzene
- Creators
- GorDan T. Reeves - Stockton UniversityAnthony W. Addison - Drexel UniversityMatthias Zeller - Youngstown State University
- Publication Details
- Polyhedron, v 179, 114367
- Publisher
- Elsevier
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Chemistry
- Web of Science ID
- WOS:000523757900024
- Scopus ID
- 2-s2.0-85078798506
- Other Identifier
- 991019168383104721
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- Collaboration types
- Domestic collaboration
- Web of Science research areas
- Chemistry, Inorganic & Nuclear
- Crystallography