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Sculpting crystals one Burgers vector at a time: Toward colloidal lattice robot swarms
Journal article   Open access   Peer reviewed

Sculpting crystals one Burgers vector at a time: Toward colloidal lattice robot swarms

Bryan VanSaders, Sharon C. Glotzer and Northwestern Univ., Evanston, IL (United States)
Proceedings of the National Academy of Sciences - PNAS, v 118(3), 2017377118
19 Jan 2021
PMID: 33431683
url
https://doi.org/10.1073/pnas.2017377118View
Published, Version of Record (VoR)Open Access (License Unspecified) Open

Abstract

Multidisciplinary Sciences Science & Technology Science & Technology - Other Topics
Plastic deformation of crystalline materials with isotropic particle attractions proceeds by the creation and migration of dislocations under the influence of external forces. If dislocations are produced and migrated under the action of local forces, then material shape change can occur without the application of surface forces. We investigate how particles with variable diameters can be embedded in colloidal monolayers to produce dislocations on demand. We find in simulation that when embedded clusters of variable diameter particles are taken through multiple cycles of swelling and shrinking, large cumulative plastic slip is produced by the creation and biased motion of dislocation pairs in the solid for embedded clusters of particular geometries. In this way, dislocations emitted by these clusters (biased "dislocation emitters") can be used to reshape colloidal matter. Our results are also applicable to larger-scale swarms of robotic particles that organize into dense ordered two-dimensional (2D) arrangements. We conclude with a discussion of how dislocations fulfill for colloids the role sought by "metamodules" in lattice robotics research and show how successive applications of shear as a unit operation can produce shape change through slicing and swirling.

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