Journal article
Some iron(III) complexes with polydentate Schiff base ligands
Inorganica Chimica Acta, v 147(1), pp 61-64
1988
Featured in Collection : UN Sustainable Development Goals @ Drexel
Abstract
The iron(III) complexes of three Schiff base ligands are studied as their chloride or perchlorate salts and their electronic spectra, EPR spectra, and electrochemical behavior reported. Two of these ligands are formed from reaction between salicylaldehyde and 9 or 12-membered tri- or tetraazalkanes. EPR evidence indicates that one of the complexes, [1,12-bis(2-hydroxybenzylidene)-(1,4,9,12-tetraazadodec- 6-ene)iron(III)]perchlorate-1,5-water, is a spin-crossover species containing both high-spin and low-spin iron(III) in equilibrium. The third ligand comes from pyrrole-2-carboxaldehyde and a tetraazadodecane.
Metrics
Details
- Title
- Some iron(III) complexes with polydentate Schiff base ligands
- Creators
- Anthony W. Addison - Drexel UniversityCurtis G. Wahlgren - Drexel University
- Publication Details
- Inorganica Chimica Acta, v 147(1), pp 61-64
- Publisher
- Elsevier
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Chemistry
- Web of Science ID
- WOS:A1988N837800011
- Scopus ID
- 2-s2.0-25044469933
- Other Identifier
- 991019173733704721
UN Sustainable Development Goals (SDGs)
This publication has contributed to the advancement of the following goals:
InCites Highlights
Data related to this publication, from InCites Benchmarking & Analytics tool:
- Web of Science research areas
- Chemistry, Inorganic & Nuclear