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Strain fields in repulsive colloidal crystals
Journal article   Open access   Peer reviewed

Strain fields in repulsive colloidal crystals

Bryan VanSaders, Julia Dshemuchadse and Sharon C. Glotzer
Physical review materials, v 2(6), 063604
22 Jun 2018
url
https://doi.org/10.1103/PhysRevMaterials.2.063604View
Published, Version of Record (VoR) Restricted

Abstract

Materials Science Materials Science, Multidisciplinary Science & Technology Technology
The concept of a local linear elastic strain field is commonly used in the metallurgical research community to approximate the collective effect of atomic displacements around crystalline defects. Here we show that the elastic strain field approximation is a useful tool in colloidal systems. For colloidal crystals with repulsive particle interaction potentials, given similar mechanical properties, sharper potentials lead to (1) free energies of deformation dominated by entropy, (2) lower variance in strain field fluctuations, (3) increased tension-compression asymmetry near dislocation core regions, and (4) smaller windows of applicability of the linear elastic approximation. We show that the window of linear behavior for entropic colloidal crystals is broadened for pressures at which the interparticle separation sufficiently exceeds the range of steep repulsive interactions.

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Web of Science research areas
Materials Science, Multidisciplinary
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