Journal article
Structural and spectroscopic characterization of an electrophilic iron nitrido complex
Journal of the American Chemical Society, v 130(32), pp 10515-10517
13 Aug 2008
PMID: 18630913
Featured in Collection : UN Sustainable Development Goals @ Drexel
Abstract
We have isolated and structurally characterized a terminal iron nitrido complex supported by a bulky tris(carbene)borate ligand. The electronic structure of this complex reveals that the a(1) LUMO (formerly Fe(d(z)2)) is strongly stabilized by reduced antibonding interactions with the carbene sigma-donor ligands and configurational mixing (hybridization) with higher lying Fe 4s and 4p atomic orbitals. This unusual bonding interaction results in a low-lying Fe nitrido acceptor orbital (LUMO) that possesses electrophilic character. Reaction with PPh3 results in nitrogen atom transfer to the phosphine, supporting a reaction mechanism involving nucleophilic attack of the triphenylphosphine HOMO at the electrophilic LUMO of the iron nitrido complex.
Metrics
Details
- Title
- Structural and spectroscopic characterization of an electrophilic iron nitrido complex
- Creators
- Jeremiah J. Scepaniak - CabotMeita D. Fulton - CabotRanko P. Bontchev - CabotEileen N. Duesler - CabotMartin L. Kirk - CabotJeremy M. Smith - Cabot
- Publication Details
- Journal of the American Chemical Society, v 130(32), pp 10515-10517
- Publisher
- American Chemical Society; Washington, DC
- Number of pages
- 4
- Grant note
- R01GM057378 / NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES; United States Department of Health & Human Services; National Institutes of Health (NIH) - USA; NIH National Institute of General Medical Sciences (NIGMS) GM-057378 / NIGMS NIH HHS; United States Department of Health & Human Services; National Institutes of Health (NIH) - USA; NIH National Institute of General Medical Sciences (NIGMS)
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Chemistry
- Web of Science ID
- WOS:000258293800033
- Scopus ID
- 2-s2.0-49449089944
- Other Identifier
- 991020902864704721
UN Sustainable Development Goals (SDGs)
This publication has contributed to the advancement of the following goals:
InCites Highlights
Data related to this publication, from InCites Benchmarking & Analytics tool:
- Collaboration types
- Industry collaboration
- Domestic collaboration
- Web of Science research areas
- Chemistry, Multidisciplinary