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Structural "delta Doping" to Control Local Magnetization in Isovalent Oxide Heterostructures
Journal article   Open access   Peer reviewed

Structural "delta Doping" to Control Local Magnetization in Isovalent Oxide Heterostructures

E. J. Moon, Q. He, S. Ghosh, B. J. Kirby, S. T. Pantelides, A. Y. Borisevich, S. J. May and Vanderbilt Univ., Nashville, TN (United States)
Physical review letters, v 119(19), pp 197204-197204
08 Nov 2017
PMID: 29219521
url
https://doi.org/10.1103/physrevlett.119.197204View
Accepted (AM)Open Access (Publisher-Specific) Open
url
https://doi.org/10.1103/PhysRevLett.119.197204View
Published, Version of Record (VoR) Open

Abstract

Physical Sciences Physics Physics, Multidisciplinary Science & Technology
Modulation and delta-doping strategies, in which atomically thin layers of charged dopants are precisely deposited within a heterostructure, have played enabling roles in the discovery of new physical behavior in electronic materials. Here, we demonstrate a purely structural "delta-doping" strategy in complex oxide heterostructures, in which atomically thin manganite layers are inserted into an isovalent manganite host, thereby modifying the local rotations of corner-connected MnO6 octahedra. Combining scanning transmission electron microscopy, polarized neutron reflectometry, and density functional theory, we reveal how local magnetic exchange interactions are enhanced within the spatially confined regions of suppressed octahedral rotations. The combined experimental and theoretical results illustrate the potential to utilize noncharge-based approaches to "doping" in order to enhance or suppress functional properties within spatially confined regions of oxide heterostructures.

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Domestic collaboration
International collaboration
Web of Science research areas
Physics, Multidisciplinary
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