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Structure of Nanocrystalline Ti3C2 MXene Using Atomic Pair Distribution Function
Journal article   Peer reviewed

Structure of Nanocrystalline Ti3C2 MXene Using Atomic Pair Distribution Function

Chenyang Shi, Majid Beidaghi, Michael Naguib, Olha Mashtalir, Yury Gogotsi and Simon J. L. Billinge
Physical review letters, v 112(12), 125501
28 Mar 2014
PMID: 24724657

Abstract

Physics, Multidisciplinary Science & Technology Physical Sciences Physics
The structures of nanocrystalline pristine, potassium hydroxide and sodium acetate intercalated new two- dimensional materials Ti C-3(2) MXenes were studied using the x- ray atomic pair distribution function technique. Pristine MXene has a hexagonal structure with a = b = 3.0505(5) angstrom, c = 19.86(2) angstrom (S.G. P63/mmc No. 194). Both hydroxyl and fluoride terminating species are present. The intercalation of K+ or Na+ ions expands the Ti3C2 layers perpendicular to the planes but shrinks the in-plane a and b lattice parameters.

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Domestic collaboration
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Physics, Multidisciplinary
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