Journal article
Substituted Tris(2-pyridylmethyl)amine Ligands for Highly Active ATRP Catalysts
ACS macro letters, v 1(8), pp 1037-1040
21 Aug 2012
PMID: 35607033
Abstract
The synthesis and application of a very active catalyst for copper-catalyzed atom transfer radical polymerizations (ATRP) with tris([(4-methoxy-2,5-dimethyl)-2-pyridyl] methyl)amine (TPMA*) ligand is reported. Catalysts with TPMA* ligands are approximately 3 orders of magnitude more active than those with tris(2-pyridylmethyl)amine (TPMA). Catalyst activity was evaluated by cyclic voltammetry, stopped-flow, and ATRP kinetics. Catalysts with TPMA* ligands perform better than those with TPMA ligands, especially at low catalyst concentrations.
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Details
- Title
- Substituted Tris(2-pyridylmethyl)amine Ligands for Highly Active ATRP Catalysts
- Creators
- Kristin Schroeder - Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USARobert T. Mathers - Carnegie Mellon UniversityJohannes Buback - Carnegie Mellon UniversityDominik Konkolewicz - Carnegie Mellon UniversityAndrew J. D. Magenau - Carnegie Mellon UniversityKrzysztof Matyjaszewski - Carnegie Mellon University
- Publication Details
- ACS macro letters, v 1(8), pp 1037-1040
- Publisher
- American Chemical Society; Washington, DC
- Number of pages
- 4
- Grant note
- CHE-1026060; CHE-1039870; CHE-0130903; DBI-9729351 / NSF; National Science Foundation (NSF) CRP Consortium at Carnegie Mellon University Deutsche Forschungsgemeinschaft (DFG); German Research Foundation (DFG)
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Materials Science and Engineering
- Web of Science ID
- WOS:000307803400024
- Scopus ID
- 2-s2.0-84866706412
- Other Identifier
- 991020531941704721
InCites Highlights
Data related to this publication, from InCites Benchmarking & Analytics tool:
- Web of Science research areas
- Polymer Science