Journal article
Superoxide-bridged binuclear complexes of rhodium(III)
Journal of the Chemical Society A: Inorganic, Physical, Theoretical, (15), pp.2523-2526
1970
Abstract
The preparations are described of the blue or purple complex compounds of formulae [ClL4Rh·O2·RhL4Cl]Y3 where L = pyridine or γ-picoline and Y = an anion, and [(H2O)L4Rh·O2·RhL4(H2O)]Y5. The presence of the superoxide bridge is demonstrated by magnetic, spectroscopic, and analytical data. Acid-base equilibria for the aquo-complexes are mentioned. An account is given of the reduction forming the peroxo-bridged dimer [ClL4Rh·O2·RhL4Cl]Y2.
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Details
- Title
- Superoxide-bridged binuclear complexes of rhodium(III)
- Creators
- A. W Addison - University of KentR. D Gillard - University of Kent
- Publication Details
- Journal of the Chemical Society A: Inorganic, Physical, Theoretical, (15), pp.2523-2526
- Publisher
- Royal Society of Chemistry
- Number of pages
- 4
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Chemistry
- Identifiers
- 991022027636204721