Journal article
Synthesis and characterisation of rhodium(III) complexes containing nitrogen heterocyclic ligands
Dalton Transactions, (5), pp.589-596
1972
Abstract
The synthesis and characterisation of complexes of the type trans-[RhL4X2]Y (L = 3 or 4-substituted pyridine, 3,5-disubstituted pyridine, isoquinoline, pyrimidine, pyrazole, thiazole, X = Cl, Br and for L = py I; Y = univalent anion) are described. Using the same catalytic method, N-methylimidazole and ammonia give complexes of the type [RhL5X]2+(X = Cl or Br), whereas 5-chloro- and 5-nitro-N-methylimidazole give complexes of the type trans-[RhL5X2]2+. All the complexes of the type trans-[RhL4X2]+ and also [RhL5Cl]2+(L =N-methylimidazole) undergo catalytic substitutions, and the nature of the products is discussed.
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Details
- Title
- Synthesis and characterisation of rhodium(III) complexes containing nitrogen heterocyclic ligands
- Creators
- A. W Addison - University of KentK Dawson - University of KentR. D Gillard - University of KentB. T Heaton - University of KentH Shaw - University of Kent
- Publication Details
- Dalton Transactions, (5), pp.589-596
- Publisher
- Royal Society of Chemistry
- Number of pages
- 8
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Chemistry
- Identifiers
- 991022027636704721