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Synthesis and oxidation of Ti2InC, Zr2InC, (Ti-0.5,Zr-0.5)(2)InC and (Ti0.5,Hf-0.5)(2)InC in air
Journal article   Peer reviewed

Synthesis and oxidation of Ti2InC, Zr2InC, (Ti-0.5,Zr-0.5)(2)InC and (Ti0.5,Hf-0.5)(2)InC in air

S. Gupta, E. N. Hoffman and M. W. Barsoum
Journal of alloys and compounds, v 426(1-2), pp 168-175
21 Dec 2006

Abstract

Chemistry Chemistry, Physical Materials Science Materials Science, Multidisciplinary Metallurgy & Metallurgical Engineering Physical Sciences Science & Technology Technology
In this paper, we report on the synthesis and oxidation behavior of Ti2InC, Zr2InC, (Ti-0.5,Hf-0.5)(2)InC and (Ti-0.5,Zr-0.5)(2)InC. The oxidation kinetics were studied thermogravimetrically in air in the 400-700 degrees C temperature range. With the exception of Ti2InC, the oxide layers formed failed to offer any oxidation resistance at 400 degrees C or higher temperatures. The reaction products are In2O3, in which some transition metal ions are probably dissolved, and the transition metal oxides. The latter are either amorphous or nanocrystalline. In the case of Ti2InC, a protective oxide was formed at 500 degrees C. However, at higher temperatures, after an incubation period, catastrophic oxidation ensued. In all cases, the oxidation occurred by the inward diffusion of oxygen. (c) 2006 Elsevier B.V. All rights reserved.

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Chemistry, Physical
Materials Science, Multidisciplinary
Metallurgy & Metallurgical Engineering
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