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Synthesis of Type I PbSe/CdSe Dot-on-Plate Heterostructures with Near-Infrared Emission
Journal article   Peer reviewed

Synthesis of Type I PbSe/CdSe Dot-on-Plate Heterostructures with Near-Infrared Emission

Kali R Williams, Benjamin T Diroll, Nicolas E Watkins, Xue Rui, Alexandra Brumberg, Robert F Klie, Richard D Schaller and Argonne National Laboratory (ANL), Argonne, IL (United States)
Journal of the American Chemical Society, v 141(13), pp 5092-5096
03 Apr 2019
PMID: 30882213
url
https://www.osti.gov/servlets/purl/1510305View
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Abstract

Zero-dimensional PbSe quantum dots are heterogeneously nucleated and grown onto two-dimensional zincblende CdSe nanoplatelets. Electron microscopy shows ad-grown dots predominantly decorate edges and corners of the nanoplatelets. Spectroscopic characterizations relate type I electronic alignment as demonstrated via photoluminescence excitation spectroscopy enhancement of near-infrared emission. Transient photoluminescence and absorption convey ultrafast transfer of excitons to the lower energy semiconductor dots. These structures combine benefits of large absorption cross sections of nanoplatelets and efficient near-infrared emission of PbSe with quantum confinement tuning of energy gap.

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Collaboration types
Domestic collaboration
Web of Science research areas
Chemistry, Multidisciplinary
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