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The Raman spectrum of Ti3SiC2
Journal article   Open access   Peer reviewed

The Raman spectrum of Ti3SiC2

M Amer, M W Barsoum, T El-Raghy, Weiss, S Leclair and D Liptak
Journal of applied physics, v 84(10), pp 5817-5819
15 Nov 1998
url
https://doi.org/10.1063/1.368849View
Published, Version of Record (VoR)Maybe Open Access (Publisher Bronze) Open

Abstract

Physical Sciences Physics Physics, Applied Science & Technology
In this paper, the Raman spectrum of Ti3SiC2 is reported and compared with that of TiC0.67. All the TiC0.67 first order Raman disorder-induced modes are active, but shifted, in Ti3SiC2. Two additional peaks at 150 and 372 cm(-1) are observed in Ti3SiC2. The former is ascribed to a shear mode between the Si and Ti planes; the origin of the latter is unknown. No second order Raman bands are detected. Micro-Raman spectroscopy also reveal the presence of approximate to 50 Angstrom graphite crystallites in samples hot pressed in graphite dies-these crystallites are not detected in samples processed by hot isostatic pressing in molten glass containers. (C) 1998 American Institute of Physics. [S0021-8979(98)06622- 5].

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Domestic collaboration
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Physics, Applied
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