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The infrared spectrum and conformation of acetone oxime vinyl ether
Journal article   Peer reviewed

The infrared spectrum and conformation of acetone oxime vinyl ether

Karl Sohlberg, Scott P. Leary, Noel L. Owen and Boris A. Trofimov
Vibrational spectroscopy, v 13(2)
1997

Abstract

Ab initio calculations Acetone oxime vinyl ether Matrix isolation spectrum Nuclear magnetic resonance spectrometry Trans rotamer
The infrared spectrum of acetone oxime vinyl ether (AOVE) has been studied for the gaseous, liquid and solid phases as well as in an inert matrix at low temperatures. HF-SCF calculations have been carried out on AOVE and they predict the presence of one dominant rotamer with a heavy atom planar ( trans) structure. The infrared spectrum is consistent with this conclusion, and assignments are made to many of the normal modes. Specific assignments have also been made for all the observed 1H and 13C NMR spectral lines.

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Collaboration types
Domestic collaboration
International collaboration
Web of Science research areas
Chemistry, Analytical
Chemistry, Physical
Spectroscopy
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