Journal article
The role of microwave absorption on formation of graphene from graphite oxide
Carbon (New York), v 50(9), pp 3267-3273
Aug 2012
Abstract
By means of manipulating the oxygen content in graphite oxides (GO) and/or graphene-based materials, we demonstrate that the microwave absorption capacity of carbon materials is highly dependent on their chemical composition and structure. The increase of oxygen in GO remarkably decreases its microwave absorption capacity due to the size decrease of the π–π conjugated structure in these materials, and vice versa. It was revealed that graphene is an excellent microwave absorbent while GO with poor microwave absorption capacity, the unoxidized graphitic region “impurities” in GO act as the microwave absorbents to initiate the microwave-induced deoxygenation. The addition of a small amount graphene to GO leads to avalanche-like deoxygenation reaction of GO under microwave irradiation (MWI) and graphene formation, which was used for electrode materials in supercapacitors. The interaction between microwaves and graphene or graphene-based materials may be used for the fabrication of a variety of graphene-based nanocomposites with exceptional properties and a wealth of practical applications.
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Details
- Title
- The role of microwave absorption on formation of graphene from graphite oxide
- Creators
- Han Hu - Carbon Research Laboratory, School of Chemical Engineering, State Key Lab of Fine Chemicals, Dalian University of Technology, Dalian 116023, ChinaZongbin Zhao - Carbon Research Laboratory, School of Chemical Engineering, State Key Lab of Fine Chemicals, Dalian University of Technology, Dalian 116023, ChinaQuan Zhou - Carbon Research Laboratory, School of Chemical Engineering, State Key Lab of Fine Chemicals, Dalian University of Technology, Dalian 116023, ChinaYury Gogotsi - Carbon Research Laboratory, School of Chemical Engineering, State Key Lab of Fine Chemicals, Dalian University of Technology, Dalian 116023, ChinaJieshan Qiu - Carbon Research Laboratory, School of Chemical Engineering, State Key Lab of Fine Chemicals, Dalian University of Technology, Dalian 116023, China
- Publication Details
- Carbon (New York), v 50(9), pp 3267-3273
- Publisher
- Elsevier
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Materials Science and Engineering
- Web of Science ID
- WOS:000304644700019
- Scopus ID
- 2-s2.0-84860659547
- Other Identifier
- 991014970028604721
InCites Highlights
Data related to this publication, from InCites Benchmarking & Analytics tool:
- Collaboration types
- Domestic collaboration
- International collaboration
- Web of Science research areas
- Chemistry, Physical
- Materials Science, Multidisciplinary