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The thermal decomposition of sodium N-chlorobenzene sulfonamide in KBr
Journal article   Peer reviewed

The thermal decomposition of sodium N-chlorobenzene sulfonamide in KBr

Larry Gelfand, Louis L. Pytlewski, Clifford Owens and Carol L Owens
Spectrochimica acta. Part A: Molecular spectroscopy, v 35(1), pp 79-82
1979

Abstract

Infrared spectra of sodium N-chlorobenzine sulfonamide 4000-250 cm −1 have been obtained on samples prepared in KBr disc and stored for several hours at 110°C. The subject compound undergoes a thermal decomposition by two mechanisms; the first is a hydrolysis of the nitrogen to chlorine bond to yield the corresponding sodium salt of benzene sulfonamide while the second involves an intramolecular rearrangement to form the sodium salt of 2-chlorobenzene sulfonamide.

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