Journal article
Thermochemical studies of sym-dichlorobis (2,4,6-trichlorophenyl) urea
Thermochimica acta, v 54(3), pp 281-287
1982
Abstract
Thermal decomposition of sym-dichlorobis (2,4,6-trichlorophenyl) urea occurs by two steps: the first at 150–184°C accompanied by a 26% weight loss and +(16.6±0.7) kcal mole
−1 and the second by a 40% weight loss and −(17.4±1.0) kcal mole
−1. The decomposition pressure follows the equation ln
p=
A +
B/
T +
C/
T
2 where
A = 149.89,
B=9.45·10 [4] and
C=1.48·10 [7]. The decomposition products are 2,4,6-trichlorophenyl isocyanate 2,4,6-trichloroaniline, chlorine, 1,2,3,5-tetrachlorobenzene, 2,2′,4,4′,6,6′-hexachlorobiphenyl, 2,2′,4,4′-tetrachlorobiphenyl, 2,2′,4,4′,6-pentachlorobiphenyl and ammonium chloride.
Metrics
Details
- Title
- Thermochemical studies of sym-dichlorobis (2,4,6-trichlorophenyl) urea
- Creators
- Clifford Owens - Rutgers, The State University of New JerseyLouis L. Pytlewski - Drexel UniversityKenneth Krevitz - Drexel UniversityThomas Mitchell - Edgewood Arsenal, Edgewood, MD 21010 U.S.A.Carol L Owens - Physical Therapy (and Rehabilitation Sciences)
- Publication Details
- Thermochimica acta, v 54(3), pp 281-287
- Publisher
- Elsevier
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Physical Therapy (and Rehabilitation Sciences)
- Web of Science ID
- WOS:A1982NL37500006
- Scopus ID
- 2-s2.0-49049130974
- Other Identifier
- 991019174897904721
InCites Highlights
Data related to this publication, from InCites Benchmarking & Analytics tool:
- Collaboration types
- Domestic collaboration
- Web of Science research areas
- Chemistry, Analytical
- Chemistry, Physical
- Thermodynamics