Journal article
Tin(IV)-catalyzed lactonization of ω-Hydroxy trifluoroethyl esters
Tetrahedron letters, v 34(22), pp 3515-3518
28 May 1993
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Abstract
Macrolactonization of 1,1,1-trifluoroethyl ester of ω-hydroxycarboxylic acids was effected with tri-
n-butylmethoxystannane and other tin(IV) reagents in refluxing octane.
1,1,1-Trifluoroethyl esters of ω-hydroxycarboxylic acids were prepared and their conversion to macrocyclic lactones, including ricinelaidic lactone, was studied in the presence of catalytic quantities of tin(IV) reagents; a mechanism involving exchange of alkoxytrialkyltin species is proposed.
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Details
- Title
- Tin(IV)-catalyzed lactonization of ω-Hydroxy trifluoroethyl esters
- Creators
- James D. White - Oregon State UniversityNeat J. Green - Oregon State UniversityFraser F. Fleming - Oregon State University
- Publication Details
- Tetrahedron letters, v 34(22), pp 3515-3518
- Publisher
- Elsevier
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Chemistry
- Web of Science ID
- WOS:A1993LE30100005
- Scopus ID
- 2-s2.0-0027174763
- Other Identifier
- 991020898392904721
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InCites Highlights
Data related to this publication, from InCites Benchmarking & Analytics tool:
- Web of Science research areas
- Chemistry, Organic