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Titanium Carbide (MXene) as a Current Collector for Lithium-Ion Batteries
Journal article   Open access

Titanium Carbide (MXene) as a Current Collector for Lithium-Ion Batteries

Chueh-Han Wang, Narendra Kurra, Mohamed Alhabeb, Jeng-Kuei Chang, Husam N Alshareef and Yury Gogotsi
ACS omega, v 3(10), pp 12489-12494
31 Oct 2018
PMID: 31457980
url
https://doi.org/10.1021/acsomega.8b02032View
Published, Version of Record (VoR) Open

Abstract

MXenes are a class of two-dimensional (2D) transition-metal carbides and nitrides that are currently at the forefront of 2D materials research. In this study, we demonstrate the use of metallically conductive free-standing films of 2D titanium carbide (MXene) as current-collecting layers (conductivity of ∼8000 S/cm, sheet resistance of 0.5 Ω/sq) for battery electrode materials. Multilayer Ti3C2T x (T x : surface functional groups −O, −OH, and −F) is used as an anode material and LiFePO4 as a cathode material on 5 μm MXene films. Our results show that the capacities and rate performances of electrode materials using Ti3C2T x MXene current collectors match those of conventional Cu and Al current collectors, but at significantly reduced device weight and thickness. This study opens new avenues for developing MXene-based current collectors for improving volumetric and gravimetric performances of energy-storage devices.

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Collaboration types
Domestic collaboration
International collaboration
Web of Science research areas
Chemistry, Multidisciplinary
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