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Triethylammonium benzene-1,3,5-tricarboxylato(pyridine)zinc(II): a two-dimensional undulating mesh network
Journal article   Peer reviewed

Triethylammonium benzene-1,3,5-tricarboxylato(pyridine)zinc(II): a two-dimensional undulating mesh network

Gang Wu, Xin Shi, Qianrong Fang, Ge Tian, Lifeng Wang, Guangshan Zhu, Anthony W. Addison, Yen Wei, Shilun Qiu and Gordon Wu
Inorganic chemistry communications, v 6(4), pp 402-404
2003

Abstract

BTC Chiral Coordination polymer Template
A two-dimensional layered metal-organic framework material (HN(CH 2CH 3) 3)Zn(BTC)(Pyd) with chiral trigonal pores has been prepared with HTEA + as the structure-directing agent under mild synthetic condition. Crystal data for (HTEA)Zn(BTC)(Pyd): M=450.77, Orthorhombic, space group Pbca, a=13.652(4) Å, b=16.345(4) Å, c=18.734(6) Å, V=4180(2) A ̊ 3 , T=293 K, Z=8, μ=1.213 mm −1 , D c =1.439 mg/m 3 . 9197 reflections measured, 2972 observed ( R int=0.0905), which were used in all calculations. The final R 1=0.0498, R ω =0.1134. The structure was solved by direct methods using SHEUXTU-97.

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Web of Science research areas
Chemistry, Inorganic & Nuclear
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