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Tuning the absorptions of Au nanospheres on a microshell by photo-deformation
Journal article   Peer reviewed

Tuning the absorptions of Au nanospheres on a microshell by photo-deformation

Li-Hsin Han, Tingji Tang and Shaochen Chen
Nanotechnology, v 17(18), pp 4600-4605
28 Sep 2006
PMID: 21727583

Abstract

We report the design, modelling, fabrication, and testing of a photo-tunable particulate medium that comprises photo-responsible polymeric microshells covered by Au nanospheres. The microshells were formed by a layer-by-layer method. The charged Au nanospheres were coated on outer surfaces of the microshells. The polymeric shells contain azobenzene moieties and shrink upon ultraviolet irradiation; therefore, the interparticle spaces between the nanospheres are tunable by UV light. The absorption spectrum of the Au nanosphere modified microshells changed drastically after the shrinkage. A decreased absorption peak of Au nanospheres and an enhanced absorption in the near-infrared region were clearly observed. The results of theoretical modelling suggest that the overall spectral changes stem mainly from the enhanced particle interactions and also from the field enhancements in the space among the nanospheres.

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Web of Science research areas
Materials Science, Multidisciplinary
Nanoscience & Nanotechnology
Physics, Applied
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