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Tuning the reactivity of TEMPO by coordination to a Lewis acid: isolation and reactivity of M[Cl.sub.3]
Journal article   Peer reviewed

Tuning the reactivity of TEMPO by coordination to a Lewis acid: isolation and reactivity of M[Cl.sub.3]

Jeremiah J Scepaniak, Ashley M Wright, Richard A Lewis, Guang Wu and Trevor W Hayton
Journal of the American Chemical Society, Vol.134(47), p19350
28 Nov 2012

Abstract

Aldehydes Analysis Chemical properties Methyl groups Oxidation-reduction reaction Thermal properties Usage X-ray crystallography
The outcomes and results caused by the addition of 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO) to M[Cl.sub.3] are analyzed in the study. The study also discusses the isolation and reactivity of the M[Cl.sub.3]([[eta].sup.1]-TEMPO) (M = Fe, Al) compounds.

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