Journal article
Two-Dimensional Titanium Carbide MXene As a Cathode Material for Hybrid Magnesium/Lithium-Ion Batteries
ACS applied materials & interfaces, Vol.9(5), pp.4296-4300
08 Feb 2017
PMID: 27275950
Featured in Collection : UN Sustainable Development Goals @ Drexel
Abstract
As an alternative to pure lithium-ion, Li
, systems, a hybrid magnesium, Mg
, and Li
battery can potentially combine the high capacity, high voltage, and fast Li
intercalation of Li-ion battery cathodes and the high capacity, low cost, and dendrite-free Mg metal anodes. Herein, we report on the use of two-dimensional titanium carbide, Ti
C
T
(MXene), as a cathode in hybrid Mg
/Li
batteries, coupled with a Mg metal anode. Free-standing and flexible Ti
C
T
/carbon nanotube composite "paper" delivered ∼100 mAh g
at 0.1 C and ∼50 mAh g
at 10 C. At 1 C the capacity was maintained for >500 cycles at 80 mAh g
. The Mo
CT
MXene also demonstrated good performance as a cathode material in this hybrid battery. Considering the variety of available MXenes, this work opens the door for exploring a new large family of 2D materials with high electrical conductivity and large intercalation capacity as cathodes for hybrid Mg
/Li
batteries.
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Details
- Title
- Two-Dimensional Titanium Carbide MXene As a Cathode Material for Hybrid Magnesium/Lithium-Ion Batteries
- Creators
- Ayeong Byeon - Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST) , 291 Daehak-ro, Yuseong-gu, Daejeon 305-701, Republic of KoreaMeng-Qiang Zhao - Department of Materials Science and Engineering and A. J. Drexel Nanomaterials Institute, Drexel University , Philadelphia, Pennsylvania 19104, United StatesChang E Ren - Department of Materials Science and Engineering and A. J. Drexel Nanomaterials Institute, Drexel University , Philadelphia, Pennsylvania 19104, United StatesJoseph Halim - Thin Film Physics Division, Department of Physics, Chemistry and Biology (IFM), Linköping University , SE-58183 Linköping, SwedenSankalp Kota - Department of Materials Science and Engineering and A. J. Drexel Nanomaterials Institute, Drexel University , Philadelphia, Pennsylvania 19104, United StatesPatrick Urbankowski - Department of Materials Science and Engineering and A. J. Drexel Nanomaterials Institute, Drexel University , Philadelphia, Pennsylvania 19104, United StatesBabak Anasori - Department of Materials Science and Engineering and A. J. Drexel Nanomaterials Institute, Drexel University , Philadelphia, Pennsylvania 19104, United StatesMichel W Barsoum - Department of Materials Science and Engineering and A. J. Drexel Nanomaterials Institute, Drexel University , Philadelphia, Pennsylvania 19104, United StatesYury Gogotsi - Department of Materials Science and Engineering and A. J. Drexel Nanomaterials Institute, Drexel University , Philadelphia, Pennsylvania 19104, United States
- Publication Details
- ACS applied materials & interfaces, Vol.9(5), pp.4296-4300
- Publisher
- American Chemical Society; Washington, DC
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Materials Science and Engineering
- Identifiers
- 991014878331504721
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- Collaboration types
- Domestic collaboration
- International collaboration
- Web of Science research areas
- Materials Science, Multidisciplinary
- Nanoscience & Nanotechnology