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Water Transport in Polylactide and Polylactide/Montmorillonite Composites
Journal article   Peer reviewed

Water Transport in Polylactide and Polylactide/Montmorillonite Composites

An Du, Genaro Gelves, Donghun Koo, Uttandaraman Sundararaj and Richard Cairncross
Journal of polymers and the environment, v 21(1)
Mar 2013

Abstract

Polymer Sciences Chemistry Montmorillonite Polylactide Exfoliation Permeation
Polylactide–montmorillonite composites were fabricated by melt-blending followed by compression molding, and water permeability of the composites was studied by both experiments and theoretical models. The water permeation in composites decreases with increasing concentration of montmorillonite. Specifically, at a concentration of 10 wt% of montmorillonite, the water permeation is 34 % less than in the neat polymer. Transmission electron microscopy (TEM) and wide-angle X-ray scattering (WAXS) results show that most of the montmorillonite particles are well-dispersed and randomly exfoliated in the polymer matrix. A fit of theoretical models to the permeation data estimates that montmorillonite platelets are mostly exfoliated in the polymer matrix and oriented randomly, which matches with results from WAXS and TEM.

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Collaboration types
Domestic collaboration
International collaboration
Web of Science research areas
Engineering, Environmental
Polymer Science
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