The growing concern about nutrient-rich diets and health monitoring has motivated the search for simple, fast, and effective methods for detecting important nutrients in foodstuffs. In this scenario, colorimetric detection using nanostructures presenting enzymatic properties (nanozymes) has gained prominence due to its experimental simplicity and low cost. In this work, zinc oxide-cobalt oxide electrospun nanofibers (ZnO-Co3O4 NFs) were combined with titanium carbide (Ti3C2Tx) MXene for the colorimetric detection of ascorbic acid. The nanocomposite (ZnO-Co3O4 NFs/Ti3C2Tx) presented peroxidase-like activity with a high affinity for the chromogenic substrate 3,3,5,5-tetramethylbenzidine and fast reaction kinetics. Taking advantage of the catalytic properties of the developed nanocomposite, ascorbic acid was detected with high sensitivity (the limit of detection was 0.58 mu mol L-1) and selectivity, even in the presence of common interferents. The colorimetric sensor even detected ascorbic acid in orange juice, revealing its potential to be used as a reliable and sensitive portable method for food analysis.
ZnO-Co3O4 Nanofibers/MXene Composite with Peroxidase-Like Activity for Ascorbic Acid Detection
Creators
Murilo H. M. Facure - Brazilian Agricultural Research Corporation
Luiza A. Mercante - Universidade Federal da Bahia
Yury Gogotsi - Drexel University
Daniel S. Correa (Corresponding Author) - Brazilian Agricultural Research Corporation
Publication Details
ACS applied nano materials
Publisher
Amer Chemical Soc
Number of pages
9
Grant note
CNPq/402.287/2013-4 / CNPq; Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPQ)
2021/11683-8; 2017/10582-8; 2018/22214-6 / Funda??o de Amparo ? Pesquisa do Estado de S?o Paulo
MCTI-SisNano
FAPESP; Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP)
Resource Type
Journal article
Language
English
Academic Unit
Materials Science and Engineering
Web of Science ID
WOS:001203974500001
Scopus ID
2-s2.0-86000425714
Other Identifier
991021871928504721
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