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Time-Temperature-Transformation (TTT) cure diagrams: Relationship between Tg and the temperature and time of cure for a polyamic acid/polyimide system (Technical Report No. 12, 31 Dec. 1984 - 31 Dec.) (1986)
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Time-Temperature-Transformation (TTT) cure diagrams: Relationship between Tg and the temperature and time of cure for a polyamic acid/polyimide system (Technical Report No. 12, 31 Dec. 1984 - 31 Dec.) (1986)

G Palmese and J Gillham
Time-Temperature-Transformation (TTT) cure diagrams: Relationship between Tg and the temperature and time of cure for a polyamic acid/polyimide system (Technical Report No. 12, 31 Dec. 1984 - 31 Dec.) (1986)
01 May 1987

Abstract

Glass transition temperatures (Tg) were obtained versus isothermal temperature (Tcure) and time of cure for a polyamic acid/polyimide system. A time temperature-transformation (TTT) isothermal cure diagram was constructed to include the time to vitrification and iso-Tg curves. As for epoxies, the relationship between Tcure and the time to vitrification is S-shaped. Plots of Tg versus Tcure show that solvent evaporation and chemical reaction are controlled by vitrification. (GRA)

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