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5,7,12,14-Tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene-6,13-diol dimethylformamide disolvate
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5,7,12,14-Tetrahydro-5,14:7,12-bis([1,2]benzeno)pentacene-6,13-diol dimethylformamide disolvate

Mohammad Nozari, Manpreet Kaur, Jerry P. Jasinski, Anthony W. Addison, Ahmad Arabi Shamsabadi and Masoud Soroush
IUCrData, v 1(7), x161130
28 Jul 2016
url
https://doi.org/10.1107/s2414314616011305View
Published, Version of Record (VoR)CC BY V4.0 Open
url
https://doi.org/10.1107/S2414314616011305View
Published, Version of Record (VoR) Open

Abstract

The crystal lattice of the title compound, C34H22O2·2C3H7NO, at 173 K has monoclinic (P21/n) symmetry. Mol­ecules are located on crystallographic centers of symmetry and have approximate non-crystallographic mmm symmetry, indicating that in solution the chemical and spectroscopic behavior would be that of a D2h mol­ecule. The compound has applications in gas-separation membranes fabricated from polymers of intrinsic microporosity (PIM). The compound is the product of reduction of the corresponding quinone by Na2S2O4 in DMF/NaHCO3.

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