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Application of quantum cascade lasers to high-precision atmospheric trace gas measurements
Journal article   Open access   Peer reviewed

Application of quantum cascade lasers to high-precision atmospheric trace gas measurements

J. Barry McManus, Mark S. Zahniser, David D. Nelson, Joanne H. Shorter, Scott Herndon, Ezra Wood and Rick Wehr
Optical engineering, v 49(11), pp 111124-111124
01 Nov 2010
url
https://doi.org/10.1117/1.3498782View
Published, Version of Record (VoR)CC BY V4.0 Open

Abstract

Optics Physical Sciences Science & Technology
We review our recent results in development of high-precision laser spectroscopic instrumentation using midinfrared quantum cascade lasers (QCLs). Some of these instruments have been directed at measurements of atmospheric trace gases where a fractional precision of 10(-3) or better of ambient concentration may be required. Such high precision is needed in measurements of fluxes of stable atmospheric gases and measurements of isotopic ratios. Instruments that are based on thermoelectrically cooled midinfrared QCLs and thermoelectrically cooled detectors have been demonstrated that meet the requirements of high-precision atmospheric measurements, without the need for cryogens. We also describe the design of and results from a new dual QCL instrument with a 200-m path-length absorption cell. This instrument has demonstrated 1-s noise of 32 ppt for formaldehyde (HCHO) and 9 ppt for carbonyl sulfide (OCS). (C) 2010 Society of Photo-Optical Instrumentation Engineers. [DOI: 10.1117/1.3498782]

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Optics
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