Published, Version of Record (VoR)CC BY V4.0, Open
Abstract
Optics Physical Sciences Science & Technology
We review our recent results in development of high-precision laser spectroscopic instrumentation using midinfrared quantum cascade lasers (QCLs). Some of these instruments have been directed at measurements of atmospheric trace gases where a fractional precision of 10(-3) or better of ambient concentration may be required. Such high precision is needed in measurements of fluxes of stable atmospheric gases and measurements of isotopic ratios. Instruments that are based on thermoelectrically cooled midinfrared QCLs and thermoelectrically cooled detectors have been demonstrated that meet the requirements of high-precision atmospheric measurements, without the need for cryogens. We also describe the design of and results from a new dual QCL instrument with a 200-m path-length absorption cell. This instrument has demonstrated 1-s noise of 32 ppt for formaldehyde (HCHO) and 9 ppt for carbonyl sulfide (OCS). (C) 2010 Society of Photo-Optical Instrumentation Engineers. [DOI: 10.1117/1.3498782]
Application of quantum cascade lasers to high-precision atmospheric trace gas measurements
Creators
J. Barry McManus - Aerodyne Research
Mark S. Zahniser - Aerodyne Research
David D. Nelson - Aerodyne Research
Joanne H. Shorter - Aerodyne Research
Scott Herndon - Aerodyne Research
Ezra Wood - Aerodyne Research
Rick Wehr - University of Arizona
Publication Details
Optical engineering, v 49(11), pp 111124-111124
Publisher
Spie-Soc Photo-Optical Instrumentation Engineers
Number of pages
11
Grant note
Department of Agriculture
Department of Energy; United States Department of Energy (DOE)
Department of Commerce
National Science Foundation; National Science Foundation (NSF)
Environmental Protection Agency
Resource Type
Journal article
Language
English
Academic Unit
Chemistry
Web of Science ID
WOS:000284996200027
Scopus ID
2-s2.0-79953865339
Other Identifier
991020902865804721
UN Sustainable Development Goals (SDGs)
This publication has contributed to the advancement of the following goals:
InCites Highlights
Data related to this publication, from InCites Benchmarking & Analytics tool: