Journal article
Engineering Ultrathin Polyaniline in Micro/Mesoporous Carbon Supercapacitor Electrodes Using Oxidative Chemical Vapor Deposition
Advanced materials interfaces, v 4(8), pp 1601201-n/a
21 Apr 2017
Featured in Collection : UN Sustainable Development Goals @ Drexel
Abstract
In this work, oxidative chemical vapor deposition (oCVD) is demonstrated to enable the integration of nanometer‐thin polyaniline (PANI) that significantly improves charge storage capacity of supercapacitors utilizing carbide‐derived carbon (CDC) with a bimodal (micro/mesoporous) pore size distribution. To our knowledge, this work is the first reported synthesis of PANI via oCVD. The oCVD process allows for the integration of PANI into pores as small as 1.7 nm, and resulting CDC/PANI electrodes have a gravimetric capacitance more than twice that of bare CDC (136 F g−1 for 11 wt% of PANI in the CDC electrode versus 60 F g−1 for bare Mo2C‐CDC at 10 mV s−1). This yields a PANI‐only gravimetric capacitance of ≈690 F g−1, which is close to the theoretical value of 750 F g−1. The coating preserves the native electrode surface area and pore size distribution, while improving capacitance due to the faradaic redox reactions of PANI. Even at high scan rates of over 100 mV s−1, the added pseudocapacitance from PANI remains evident. The composite electrode exhibits good cyclability, decreasing to 90% of the initial value (≈100 F g−1) after 10 000 cycles.
Novel oxidative chemical vapor deposition (oCVD) synthesis and integration of ultrathin polyaniline (PANI) into micro/mesoporous carbide‐derived carbon (Mo2C‐CDC) supercapacitor electrodes. A combination of spectroscopic techniques confirms that the oCVD process produces electrochemically active emeraldine PANI. The composite electrode exhibits a two times improvement in specific capacitance versus bare Mo2C‐CDC and shows good cyclability.
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Details
- Title
- Engineering Ultrathin Polyaniline in Micro/Mesoporous Carbon Supercapacitor Electrodes Using Oxidative Chemical Vapor Deposition
- Creators
- Yuriy Y Smolin - Drexel UniversityKatherine L Van Aken - Drexel UniversityMuhammad Boota - Drexel UniversityMasoud Soroush - Drexel UniversityYury Gogotsi - Drexel UniversityKenneth K. S Lau - Drexel University
- Publication Details
- Advanced materials interfaces, v 4(8), pp 1601201-n/a
- Publisher
- Wiley
- Number of pages
- 8
- Grant note
- National Science Foundation (CBET‐1236180) U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences for research
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Materials Science and Engineering; Chemical and Biological Engineering
- Web of Science ID
- WOS:000400778100010
- Scopus ID
- 2-s2.0-85016419504
- Other Identifier
- 991014969869504721
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InCites Highlights
Data related to this publication, from InCites Benchmarking & Analytics tool:
- Web of Science research areas
- Chemistry, Multidisciplinary
- Materials Science, Multidisciplinary