Fluorescent composite fibrous assembles of nanoparticle-polyelectrolyte fibers are useful multifunctional materials, utilized in filtration, sensing and tissue engineering applications, with the added benefits of improved mechanical, electrical or structural characteristics over the individual components. Composite fibrous mats were prepared by electrospinning aqueous solutions of 6 wt% poly(acrylic acid) (PAA) loaded with 0.15 and 0.20% v/v, carboxyl functionalized CdSe/ZnS nanoparticles (SNPs). The resulting fluorescent composite fibrous mats exhibits recoverable quenching when exposed to high humidity. The sensor response is sensitive to water concentration and is attributed to the change in the local charges around the SNPs due to deprotonation of the carboxylic acids on the SNPs and the surrounding polymer matrix.
Fabrication and Characterization of Electrospun Semiconductor Nanoparticle-Polyelectrolyte Ultra-Fine Fiber Composites for Sensing Applications
Creators
Jennifer S. Atchison - Drexel University
Caroline L. Schauer - Drexel University
Publication Details
Sensors (Basel, Switzerland), v 11(11), pp 10372-10387
Publisher
Mdpi
Number of pages
16
Grant note
CMMI 0804543; DUE 0942834 / National Science Foundation; National Science Foundation (NSF)
0804543 / Div Of Civil, Mechanical, & Manufact Inn; National Science Foundation (NSF); NSF - Directorate for Engineering (ENG)
Resource Type
Journal article
Language
English
Academic Unit
Materials Science and Engineering; Mechanical Engineering and Mechanics
Web of Science ID
WOS:000297698600022
Scopus ID
2-s2.0-82055194292
Other Identifier
991019168970604721
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