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Fabrication and Characterization of Electrospun Semiconductor Nanoparticle-Polyelectrolyte Ultra-Fine Fiber Composites for Sensing Applications
Journal article   Open access   Peer reviewed

Fabrication and Characterization of Electrospun Semiconductor Nanoparticle-Polyelectrolyte Ultra-Fine Fiber Composites for Sensing Applications

Jennifer S. Atchison and Caroline L. Schauer
Sensors (Basel, Switzerland), v 11(11), pp 10372-10387
01 Nov 2011
PMID: 22346647
url
https://doi.org/10.3390/s111110372View
Published, Version of Record (VoR)CC BY V4.0 Open

Abstract

Chemistry Chemistry, Analytical Engineering Engineering, Electrical & Electronic Instruments & Instrumentation Physical Sciences Science & Technology Technology
Fluorescent composite fibrous assembles of nanoparticle-polyelectrolyte fibers are useful multifunctional materials, utilized in filtration, sensing and tissue engineering applications, with the added benefits of improved mechanical, electrical or structural characteristics over the individual components. Composite fibrous mats were prepared by electrospinning aqueous solutions of 6 wt% poly(acrylic acid) (PAA) loaded with 0.15 and 0.20% v/v, carboxyl functionalized CdSe/ZnS nanoparticles (SNPs). The resulting fluorescent composite fibrous mats exhibits recoverable quenching when exposed to high humidity. The sensor response is sensitive to water concentration and is attributed to the change in the local charges around the SNPs due to deprotonation of the carboxylic acids on the SNPs and the surrounding polymer matrix.

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Web of Science research areas
Chemistry, Analytical
Engineering, Electrical & Electronic
Instruments & Instrumentation
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