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Ferroelectricity in chemical nanostructures: proximal probe characterization and the surface chemical environment
Journal article   Peer reviewed

Ferroelectricity in chemical nanostructures: proximal probe characterization and the surface chemical environment

Stephen Nonnenmann and Jonathan Spanier
Journal of materials science, v 44(19), pp 5205-5213
Oct 2009

Abstract

Polymer Sciences Crystallography and Scattering Methods Materials Science Electrostatic Force Microscopy Ferroelectric Polarization Materials Science, general Solid Mechanics BaTiO3 Classical Mechanics Characterization and Evaluation of Materials Piezoresponse Force Microscopy Converge Beam Electron Diffraction
Renewed interest in the evolution of the ferroelectric phase transition temperature TC and the character of ordering of ferroelectric polarizations with finite size and shape is driven in part by several recent developments. An expanding array of pathways for producing nano-structured ferroelectric oxides with control of size, shape, and composition has emerged. Experimental characterization methods originally developed for thin films have been extended to ensemble-free investigations of functional properties of individual nanostructures. Progress in understanding the origin and nature of ferroelectric stability in ultra-thin films and nanostructures is reviewed. Specifically, we discuss evidence for a new surface adsorbate-driven mechanism for stabilizing ferroelectricity in nanostructures owing to a combination of recent proximal probe analysis and model calculation results, along with a new experimental paradigm for investigating and exploiting these effects and effects of finite curvature.

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Web of Science research areas
Materials Science, Multidisciplinary
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