Journal article
Next generation polymers of intrinsic microporosity with tunable moieties for ultrahigh permeation and precise molecular CO2 separation
Progress in energy and combustion science, v 84, 100903
May 2021
Featured in Collection : UN Sustainable Development Goals @ Drexel
Abstract
Polymers of intrinsic microporosity (PIMs) with high free volumes have been synthesized by incorporating contorted rigid moieties into polymers backbones. Despite their many appealing properties, membranes made of these polymers have not been used industrially because of their fast physical aging. The unprecedented CO2 permeability and satisfactory CO2/N2 and CO2/CH4 selectivity of PIMs have led to establishing the new 2019 upper bounds for the gas mixtures. This article reviews recent advances in the field of PIM-based membranes. It discusses polymer synthesis strategies to modify PIM structures such that the resulting membranes have improved CO2 separation performance and lower physical aging. The strategies include the use of monomers with suitable side chains, kinked moieties, and stable structures.
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Details
- Title
- Next generation polymers of intrinsic microporosity with tunable moieties for ultrahigh permeation and precise molecular CO2 separation
- Creators
- Ahmad Arabi Shamsabadi - Department of Chemical and Biological Engineering, Drexel University, Philadelphia, PA 19104, USAMashallah Rezakazemi - University of ShahroodFarzad Seidi - Nanjing Forestry UniversityHossein Riazi - Drexel UniversityTejraj Aminabhavi - Pharmaceutical Engineering, Sonia College of Pharmacy, Dharwad 580 002, IndiaMasoud Soroush - Drexel University
- Publication Details
- Progress in energy and combustion science, v 84, 100903
- Publisher
- Elsevier
- Resource Type
- Journal article
- Language
- English
- Academic Unit
- Chemical and Biological Engineering
- Web of Science ID
- WOS:000632423900001
- Scopus ID
- 2-s2.0-85100728988
- Other Identifier
- 991019167918304721
UN Sustainable Development Goals (SDGs)
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- Collaboration types
- Domestic collaboration
- International collaboration
- Web of Science research areas
- Energy & Fuels
- Engineering, Chemical
- Engineering, Mechanical
- Thermodynamics