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On Raman scattering from selected M2AC compounds
Journal article   Peer reviewed

On Raman scattering from selected M2AC compounds

Oren D. Leaffer, Surojit Gupta, Michel W. Barsoum and Jonathan E. Spanier
Journal of materials research, v 22(10), pp 2651-2654
Oct 2007

Abstract

Layered Raman spectroscopy Metal
We report on the one-phonon Raman scattering spectra from the following M2AC MAX-phase ternary carbides: Ti2AlC, V2AlC, Cr2AlC, Nb2AlC, Ta2AlC, Ti2InC, Hf2InC, V2GeC, Cr2GeC, V2AsC, and Nb2AsC. We also report the results of calculations of the Γ-point, Raman-active phonon energies for these phases based on density functional theoretical simulations, including the effect of the k-point sampling on the convergence of phonon energies. Good agreement between all measured and calculated Γ-point Raman-active optical phonon energies is obtained.

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Materials Science, Multidisciplinary
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