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Stoichiometry of LaAlO3 films grown on SrTiO3 by pulsed laser deposition
Journal article   Peer reviewed

Stoichiometry of LaAlO3 films grown on SrTiO3 by pulsed laser deposition

M. Golalikhani, Q. Y. Lei, G. Chen, J. E. Spanier, H. Ghassemi, C. L. Johnson, M. L. Taheri and X. X. Xi
Journal of applied physics, v 114(2)
14 Jul 2013

Abstract

Physical Sciences Physics Physics, Applied Science & Technology
We have studied the stoichiometry of epitaxial LaAlO3 thin films on SrTiO3 substrate grown by pulsed laser deposition as a function of laser energy density and oxygen pressure during the film growth. Both x-ray diffraction (theta-2 theta scan and reciprocal space mapping) and transmission electron microscopy (geometric phase analysis) revealed a change of lattice constant in the film with the distance from the substrate. Combined with composition analysis using x-ray fluorescence we found that the nominal unit-cell volume expanded when the LaAlO3 film was La-rich, but remained near the bulk value when the film was La-poor or stoichiometric. La excess was found in all the films deposited in oxygen pressures lower than 10(-2) Torr. We conclude that the discussion of LaAlO3/SrTiO3 interfacial properties should include the effects of cation off-stoichiometry in the LaAlO3 films when the deposition is conducted under low oxygen pressures. (C) 2013 AIP Publishing LLC.

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Collaboration types
Domestic collaboration
Web of Science research areas
Physics, Applied
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